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This section provides an overview for methyl benzoate as well as their applications and principles. Also, please take a look at the list of 11 methyl benzoate manufacturers and their company rankings. Here are the top-ranked methyl benzoate companies as of December, 2024: 1.KANTO CHEMICAL CO.,INC., 2.BERJÉ INC, 3.Merck.
Table of Contents
Methyl benzoate is a colorless liquid characterized by an aromatic odor.
Also known under the IUPAC designation methyl benzoate, this organic compound is alternately known as methylbenzoate, benzoic acid methyl ester, or Niobe oil.
With the chemical formula C8H8O2 and a molecular weight of 136.15, its CAS registration number is 93-58-3. It is classified as a hazardous substance under various safety laws.
This ester compound, recognized for its fruity aroma, is naturally present in guava, mango, and kiwi fruit. It finds applications in food flavoring and the composition of ylang-ylang-based fragrances and perfumes due to its distinct aroma.
Additionally, methyl benzoate serves various purposes, including acting as a solvent for synthetic resins, cellulose esters, and rubber, assisting in the dyeing of polyester fibers, and as a component in fungicides and pesticides. Male orchid bees collect methyl benzoate from plants for use in pheromone synthesis.
In chemical synthesis, it serves as a precursor for:
As a liquid, it has a melting point of -15°C, a boiling point of 199.6°C, a flash point of 82°C, and a density of 1.094 g/cm3 at room temperature. Its lipophilic nature allows for high solubility in ethanol and acetone, while it remains insoluble in water.
The reactivity of methyl benzoate varies, targeting either the ring or the ester groups based on the reactants employed. For instance, nitration with nitric acid under acidic conditions yields 3-nitro methyl benzoate. Similarly, its carbonyl carbon's susceptibility to nucleophilic attack facilitates hydrolysis with NaOH solution to produce sodium benzoate.
Methyl benzoate can be synthesized through Fischer's esterification, reacting benzoic acid with methanol in the presence of a minimal amount of a strong acid catalyst, such as sulfuric acid.
Naturally, it is extracted from specific aquatic plants, like the Japanese pepper tree.
Handling
Being a flammable substance, methyl benzoate should be kept away from ignition sources such as high temperatures, open flames, and sparks. Its vapors may ignite from electrostatic discharge.
Appropriate grounding or other anti-static measures are advisable. Utilize in well-ventilated areas, preferably in a fume hood, and always wear personal protective equipment.
Fire Response
Thermal decomposition from fire can produce hazardous gases like carbon dioxide and carbon monoxide. Employ water spray, foam, powder extinguishers, carbon dioxide, or sand to combat fires.
Skin Contact
Avoid direct skin contact by wearing suitable protective clothing and gloves, ensuring that sleeves remain unrolled to prevent skin exposure.
In case of contact, cleanse with soap and ample water. Remove and isolate contaminated clothing. Seek medical advice if skin irritation develops.
Eye Contact
Use protective eyewear or goggles. If contact occurs, rinse your eyes thoroughly with water. Remove contact lenses if easily possible and continue rinsing. Seek medical attention if irritation persists.
Storage
Store in a glass container with a tight seal in a well-ventilated, cool location away from direct sunlight. Keep away from strong oxidizers.
*Including some distributors, etc.
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Berjé Inc. was originally founded in 1949 and is headquartered in Carteret, New Jersey. The company is a national wholesaler of over 2000 essential oils and aromatic chemicals sourced from local farmers around the world. The company has two product categories: essential & fixed oils and aromatic chemicals. Essential & fixed oils include essential oils and fixed oils while aromatic chemicals include natural aromatics and all aromatic chemicals. The company lists chemicals by four application categories which are flavor ingredients, fragrance ingredients, functional ingredients, and fragrances.
Kanto Chemical Co. Inc., founded in 1944 and headquartered in Tokyo, Japan, is a reagent manufacturer with overseas affiliates in other countries, including China, France, USA, Taiwan, and Malaysia. Its product portfolio includes analytical reagents, ionic liquids, Iodine compounds, ultra-pure chemicals, and water analysis kits. The company is also developing regenerative medicine and genetics reagents and has over 50,000 products. It has several certifications, including ISO 9001, acquired in 1994, making it the first Japanese company in the reagent industry. Other certifications are ISO 14001, ISO 13485, and ISO/IEC 17025.
Kishida Chemical Co. Ltd., established in 1924 and headquartered in Osaka, Japan, is a manufacturer of reagents and high-purity chemicals and also does drug discovery support activities. Its product portfolio includes fine chemicals, research chemicals, ionic liquid, organic micro-analytical reagents, and chemical reagents for analysis. The products support several industries, including reagent business, battery material, drug discovery, and life science. The company is ISO 14001 certified and supplies several companies worldwide, including Meterion Advanced Chemicals Inc., Acros Organics, ChemBridge Corporation, Decon Laboratories, and InerBioScreen Ltd.
A.B. Enterprises was established in 1984 and is headquartered in Maharashtra, India. The company is a manufacturer and supplier of general chemicals, specialties, and industrial chemicals to a broad range of industries including food, textile, plastic, rubber, and other industries. The company exports primarily to Canada, Bahrain, and Dubai. The company’s five major product segments include petrochemicals, food chemicals, laboratory chemicals, water treatment chemicals, and fine chemicals. In addition, the company manufactures dentistry materials, pesticides, and chemical supplies.
Merck, started in 1668 and based in Darmstadt, Germany, is a supplier of solutions and services for research, development, and manufacture of pharmaceutical and biotechnological drug therapies. The company serves the life science industry and has a broad portfolio of 300,000 products, including biopharmaceutical manufacturing, industrial microbiology, reagent, life science research, and water purification products. It is available in 66 countries, brings together six brands, and has several ISO certifications, including ISO 13485, ISO 14001, ISO 13485, and ISO 50001.
Nacalai Tesque Inc., founded in 1846 and headquartered in Kyoto, Japan, is a manufacturer of research chemicals, fine chemicals, diagnostics, and the related instruments. Some of its products include cytokines, nucleic acid electrophoresis, cell dissociation reagents, and sialic acid-related products, and it also offers custom and bulk service for bulk reagents and cell culture media. The company has more than 50 domestic distributors and several worldwide, including Asia, the Middle East, Oceania, Europe, and Africa. It is ISO 9001 and ISO 9002 certified, while the Kyoto South brand and Tesque factory are ISO 14001 certified.
Odowell is a Chinese company that specializes in the production and distribution of health wellness products. Established in 2004, the main products include blood glucose meters, blood pressure monitors, and infrared thermometers. ODOWELL provides affordable healthcare solutions to customers worldwide. With research and development, the company has earned a reputation for innovation and reliability in the healthcare industry. ODOWELL's customer satisfaction and its dedication to improving healthcare globally make it a reputable brand.
Founded in 1981, Central Drug House Ltd. serves the scientific community via manufacturing and marketing a library of over 9,000 products to laboratory fine chemicals and dehydrated culture media with emphasis on purity and service. Examples are acids & bases, adsorbents, disinfectants, indicator papers, oils, and solvents. CDH provides bio chemicals, research chemicals, laboratory reagents, various solvents, stains & indicators, and dehydrated culture media. CDH is ISO 9001 certified and CDHs’ products are in compliance with specifications of IP, BP, USP, and EP standards.
BioCrick Co., Ltd is located in Chengdu Tianfu Life Science Park in Sichuan Province, China. The company creates a natural product library which provides small molecular compounds with potential biological and pharmacological activities for pharmaceutical, agricultural, and biotechnology companies worldwide. The company’s database includes more than 8,000 compounds collected from natural sources such as as medicinal plants, herbs, fungus, and microbes. The company also a provider of peptides and lab reagents for biological research, carrying a product line in apoptosis, epigenetic, and cancer biology.
Vizag Chemical International was founded in Andhra Pradesh, India, in 2011. Vizag Chemical International sells chemical-based products for many sectors including automotive, agriculture, airline, deodorizers, construction chemicals, boat maintenance, degreasers, detergents, drain clean products, greases, personal hygiene, lab chemicals and equipment, fuel treatment, metal treatment, tank cleaners, swimming pool and spa chemicals, scale removers, sewage chemical treatment, as well as raw chemicals. Vizag Chemical International also provides a range of services including chemical inspection, logistics, chemical usage supervision, as well as tank cleaning.
Ranking as of December 2024
Derivation Method| Rank | Company | Click Share |
|---|---|---|
| 1 | KANTO CHEMICAL CO.,INC. |
24.2%
|
| 2 | BERJÉ INC |
18.2%
|
| 3 | Merck |
15.2%
|
| 4 | A. B. Enterprises |
9.1%
|
| 5 | Kishida Chemical Co.,Ltd. |
9.1%
|
| 6 | Ganesh Benzoplast Ltd. |
6.1%
|
| 7 | BioCrick |
6.1%
|
| 8 | KUNSHAN ODOWELL CO.,LTD |
6.1%
|
| 9 | Vizag Chemical International |
3.0%
|
| 10 | Central Drug House |
3.0%
|
Derivation Method
The ranking is calculated based on the click share within the methyl benzoate page as of December 2024. Click share is defined as the total number of clicks for all companies during the period divided by the number of clicks for each company.Number of Employees
Newly Established Company
Company with a History
*Including some distributors, etc.
*Including some distributors, etc.
| Country | Number of Companies | Share (%) |
|---|---|---|
|
Japan
|
3 | 37.5% |
|
India
|
3 | 37.5% |
|
United States of America
|
1 | 12.5% |
|
China
|
1 | 12.5% |
