This section provides an overview for phosphine as well as their applications and principles. Also, please take a look at the list of 10 phosphine manufacturers and their company rankings. Here are the top-ranked phosphine companies as of November, 2024: 1.Parchem, 2.Daken Chemical Limited, 3.Resins & Allied Products.
Table of Contents
Phosphine, also known as hydrogen phosphide or phosphorus hydride, is an inorganic compound consisting of hydrogen and phosphorus. Its chemical formula is PH3, with a molecular weight of 34.0 g/mol. Its boiling point is -88°C, its density as a gas is 1.38 g/L, and its CAS number is 7803-51-2. Phosphine includes derivatives of phosphine as well.
It is colorless at room temperature and exists as a flammable gas with an unpleasant odor. Its solubility in water is 26 ml per 100 L.
Phosphine is a crucial raw material in semiconductor manufacturing. Its non-covalent electron pairs and electron-rich nature make it an ideal doping agent for converting silicon into n-type semiconductors. It's also used to introduce impurities in the production of semiconductors like InGaP (indium gallium phosphide).
These semiconductors are utilized in laser diodes for optical discs such as DVDs, fiber optic communications, light receiving diodes, high brightness light emitting diodes, and electronic devices for cell phones.
Through the pyrolysis of high-purity phosphine gas, yellow phosphorus is synthesized, and further heating produces red phosphorus. Phosphine serves as a raw material for a broad spectrum of phosphorus-containing compounds due to its versatility in undergoing radical addition, Michael addition, acid catalysis, and substitution reactions.
Additionally, the proportion of primary, secondary, and tertiary phosphines can be adjusted by modifying the reaction conditions, such as the molar ratio of olefins. Secondary phosphines are oxidized to produce phosphinic acid, used in surface treatments, metal extractions, resin additives, and as a catalyst in reactions.
Primarily used in grain storage for fumigation, phosphine effectively controls pests and serves as a fungicide/sterilant. Its ability to evenly disperse through the air allows it to penetrate deep into objects and seed husks.
Phosphine's structure is similar to ammonia's, containing nitrogen from group 15 of the periodic table. However, phosphine's noncovalent electron pairs are weaker in proton affinity, making it a very weak base compared to ammonia.
Phosphine production includes methods such as reacting tricalcium diphosphide with water and generating crude phosphine gas (a mixture of phosphine and hydrogen gas) by adding sodium hydroxide to yellow phosphorus.
Phosphine is found in trace amounts in the Earth's atmosphere, believed to originate from the biological decomposition of organic matter. It is also detected in Jupiter's atmosphere, where it is thought to be produced internally. In Jupiter's environment, phosphine continually reacts with other substances.
Phosphine can spontaneously ignite upon reacting with oxygen in the air at room temperature, posing explosion risks. It is extremely toxic, capable of causing pulmonary edema, and potentially fatal if inhaled. It must be strictly stored in cylinders, avoiding any contact with human skin, mouth, or eyes. Phosphine is classified as a poisonous substance under safety laws, and in the GHS classification, it is listed as class 1 for flammability, acute toxicity, and specific target organ toxicity.
*Including some distributors, etc.
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Parchem was founded in 1999 and headquartered in Rochelle, New York. Parchem is a distributor of industrial chemicals. Parchem serves nutritional, personal care, pharmaceutical, and specialty chemical industries. Parchem offerings include coatings, adhesives, elastomers, industrial products, petrochemicals, oleochemicals, plastics, rubber, nutritional supplements, cosmetics, consumer products, catalysts, metallic salts, rare earths, flavors & fragrances, industrial & institutional, textiles, other food-related chemicals, dyes, finishes, chemicals for aerospace, oil gas drilling chemicals, electronics, and pharmaceuticals.
Zhengzhou Alfa Chemical Co., Ltd. (ZACC) is a manufacturer of organic chemicals and catalysts established in 2010 and based in Jiaozuo, Henan. The company primarily produces pharmaceutical and organic intermediates as well as photoelectric materials for customers in life science, polymers, dyes, and metallurgy. The company's product lineup includes condensed ring compounds, heterocyclic compounds, COFS/MOFS, and metal catalysts. These supply client corporations such as Bayer AG, Pfizer Inc., and Sumitomo Chemical Company, Ltd. ZACC also offers gram- to ton-level contract synthesis and production services.
Daken Chemical Limited is a manufacturer of specialty chemicals. It is headquartered in Zhengzhou, China, and was established in 1983. The company produces a range of specialty chemicals, including organic silanes, fluorochemicals, and functional monomers. Some of its popular products include Electronic Chemicals, OLED Intermediates, LCD Monomers, Photoresist Monomers and Chiral Dopants. Daken Chemical Limited also provides technical support and training services. Its products are used in many industries, including electronics, plastics, and paints.
FujiFilm Wako Pure Chemical Corporation, founded in 1922 and headquartered in Osaka, Japan, is a manufacturer of laboratory chemicals, specialty chemicals, and clinical diagnostic reagents. The company has three business domains, namely laboratory chemicals, specialty chemicals, and clinical diagnostic reagents, and some of its products include biochemistry reagents, blood transfusion test drugs, battery materials, polymer-related materials, and general reagents. The products are useful in various fields, including electronic, cosmetic, polymeric, pharmaceutical, and medical care. It acquired Sibayagi Co. Ltd. in 2015 and provides custom manufacturing to meet customer requirements.
Resins & Allied Products, established in 1998 in Mumbai, India, is a manufacturer and exporter of specialty chemicals, pharmaceutical ingredients, and drug intermediates supplied to countries such as the USA, UK, Switzerland, Denmark, and Brazil. The manufacturing facility has equipment like centrifugal machines, a thermo pack, steam-jet ejectors, a cooling tower, and a crystallizer used to make potassium phthalimide, homophthalic acid, homophthalic anhydride, benzyl chloro acetate, and sodium diethyldithiocarbamate. The company’s products have been credited by ISO 9001: 2015 Certification.
Nippon Chemical Industrial Co. Ltd., started in 1893 and headquartered in Tokyo, Japan, is a manufacturer of inorganic and specialty chemicals. In 1950, the company started the production of phosphate fertilizer at the Koriyama factory and the production of insecticides at the Miharu factory. In 1970, it began producing phosphoric acid, and in 1971, it started making chromium compounds. Its portfolio includes chromium compounds, inorganic phosphorus compounds, electronic ceramic materials, pharmaceutical intermediates, and agrochemicals. It also offers custom manufacturing for various industries, including agricultural chemicals, semiconductors, and pharmaceuticals.
Bhagwati Chemicals was founded in 2002 in Gujarat, India is a manufacturer and exporter of industrial and fine chemicals. The company operates in segments such as industrial acids, safety products, metal pretreatment chemicals, chemical supplies, and organic fertilizers. Their safety products segment includes recyclable driving gloves, shoe covers, and safety coves. The company has grown to incorporate the importation of agrochemicals like potassium humate, amino acid powder, fulvic acid 80%, and seaweed extract flakes from China and Taiwan. The company is a trader and supplier of hydrogen peroxides, formic acid, acetic acid, caustic soda flakes, glycerin, and ethylene glycol.
Founded in 1981, Central Drug House Ltd. serves the scientific community via manufacturing and marketing a library of over 9,000 products to laboratory fine chemicals and dehydrated culture media with emphasis on purity and service. Examples are acids & bases, adsorbents, disinfectants, indicator papers, oils, and solvents. CDH provides bio chemicals, research chemicals, laboratory reagents, various solvents, stains & indicators, and dehydrated culture media. CDH is ISO 9001 certified and CDHs’ products are in compliance with specifications of IP, BP, USP, and EP standards.
Founded in Mumbai, India in 2006, Otto Chemie Pvt. Ltd. is an ISO 9001:2015 & GMP certified chemical manufacturing company and distributor. Otto Chemie serves customers in many industries including agriculture and food processing, pharmaceuticals, oil & gas, cement, as well as educational and R&D industries. Product offerings include antibiotics, amino acids, vitamins, detergents, ionic liquids, materials science compounds, labware, oil, metal & ceramic science compounds and tools, oils, reagents, solvents.
Ranking as of November 2024
Derivation MethodRank | Company | Click Share |
---|---|---|
1 | Parchem |
25.8%
|
2 | Daken Chemical Limited |
21.3%
|
3 | Resins & Allied Products |
10.1%
|
4 | BHAGWATI CHEMICALS |
10.1%
|
5 | FUJIFILM Wako Pure Chemical Corporation |
7.9%
|
6 | Zhengzhou Alfa Chemical Co.,Ltd |
6.7%
|
7 | Otto Chemie Pvt. Ltd |
6.7%
|
8 | NIPPON CHEMICAL INDUSTRIAL CO.,LTD. |
6.7%
|
9 | ChemBK |
4.5%
|
Derivation Method
The ranking is calculated based on the click share within the phosphine page as of November 2024. Click share is defined as the total number of clicks for all companies during the period divided by the number of clicks for each company.Number of Employees
Newly Established Company
Company with a History
*Including some distributors, etc.
*Including some distributors, etc.
Country | Number of Companies | Share (%) |
---|---|---|
India | 3 | 37.5% |
China | 2 | 25.0% |
Japan | 2 | 25.0% |
United States of America | 1 | 12.5% |