This section provides an overview for cyclohexanone as well as their applications and principles. Also, please take a look at the list of 10 cyclohexanone manufacturers and their company rankings. Here are the top-ranked cyclohexanone companies as of November, 2024: 1.SHANDONG SUNXI NEW MATERIAL CO.,LTD, 2.SANKYO CHEMICAL CO.,LTD., 3.KANTO CHEMICAL CO.,INC..
Table of Contents
Cyclohexanone is an organic compound with the molecular formula C6H10O. It is a cyclic ketone with one methylene group of cyclohexane replaced by a carbonyl group. It is also known as ketohexamethylene, pimelic ketone, cyclohexyl ketone, hexanon, etc. Its CAS registration number is 108-94-1.
The Beckmann rearrangement of cyclohexanone oxime also produces caprolactam, an intermediate in the manufacture of 6-nylon and 6,6-nylon.
The main uses of Cyclohexanone are as follows:
In particular, the majority of applications are as raw materials for 6-nylon and 6,6-nylon. It is sometimes used as a solvent or as an activator for oxidation reactions.
Cyclohexanone has a molecular weight of 98.14, a melting point of -32.1 °C, and a boiling point of 156 °C. It is a colorless liquid with a characteristic odor at room temperature. It is said to have an odor similar to that of camphor-like acetone. If left for a long period of time, it oxidizes and turns yellow.
It is extremely soluble in ethanol and diethyl ether and slightly soluble in water. Its density is 0.9478 g/cm3.
The types of cyclohexanone generally available include reagent products for research and development, industrial chemicals, and fine chemicals. R&D reagent products are often used as raw materials for organic synthesis and as solvents.
The capacities include 500 mL, 15 kg, 17 kg, etc. These products are sold in relatively large capacities among reagent products.
In industrial products such as industrial chemicals and fine chemicals, it is offered in oil cans (16 kg), drums (190 kg), containers (1,000 L), and other packing formats.
Several methods for synthesizing cyclohexanone have been reported, the first of which is the oxidation of cyclohexanone. This reaction is catalyzed by cobalt or manganese acetates or naphthenates. A mixture of cyclohexanone and cyclohexanol is formed, which can be separated by distillation if cyclohexanone is to be isolated.
Other methods include dehydrogenation of cyclohexanol at 400-450°C using a zinc or copper catalyst and hydrogenation of phenol at 140-170°C in the gas phase using a palladium catalyst such as Pd-CaO/Al2O3.
One of the useful chemical reactions of cyclohexanone is the synthesis of nylon raw materials.
ε-caprolactam, the raw material for 6-nylon, is synthesized as follows:
Ring opening also occurs by the reaction of a mixture of cyclohexanone and cyclohexanol with nitric acid oxidation, resulting in the synthesis of adipic acid. Adipic acid is a substance used as a raw material for 6,6-nylon.
Cyclohexanone is a stable substance under normal storage and handling in accordance with regulations. There is a risk of fire or explosion when reacting with strong oxidizers such as nitric acid.
When storing, it is necessary to avoid mixing with such strong oxidizers. At temperatures above 44°C, an explosive vapor/air mixture may be generated.
Cyclohexanone is a highly flammable liquid/vapor with a flash point of 44°C (sealed). In terms of toxicity to the human body, it is toxic in contact with the skin, toxic by inhalation, irritating to the skin, irritating to the eyes, suspected of causing genetic disorders, and causing damage to the respiratory and central nervous systems.
*Including some distributors, etc.
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Sankyo Chemical Co. LTD., established in 1957 and headquartered in Nagoya, Japan, is a manufacturer of several intermediate materials, including paints, industrial cleaning agents, thinners, organic industrial chemicals, and adhesives. The products can be used in several areas, including silk screen printing, wiping off resin, washing agents for flux, metal processing, and mold forming. The company accepts contract manufacturing and provides several environmentally friendly products that comply with ISO 14001, the Industrial Safety and Health Law, and the PRTR (Pollutant Release and Transfer Register) Law.
Kanto Chemical Co. Inc., founded in 1944 and headquartered in Tokyo, Japan, is a reagent manufacturer with overseas affiliates in other countries, including China, France, USA, Taiwan, and Malaysia. Its product portfolio includes analytical reagents, ionic liquids, Iodine compounds, ultra-pure chemicals, and water analysis kits. The company is also developing regenerative medicine and genetics reagents and has over 50,000 products. It has several certifications, including ISO 9001, acquired in 1994, making it the first Japanese company in the reagent industry. Other certifications are ISO 14001, ISO 13485, and ISO/IEC 17025.
Shandong Sunxi, established in 2012, is a chemical manufacturer based in Shandong Province, China. It manufactures fine chemicals, lubricating oil, disinfectants, and silicone-based products such as methyl silica gel and silicone waterproofing and coupling agents under five different brands. The company also provides services for the development and production of custom chemical solutions both domestically and internationally. It maintains certifications for the composition and origin of its products and the safe transport of chemical goods.
Gujarat State Fertilizers & Chemicals Limited, founded in Vadodara, Gujarat, in 1962 is a manufacturer of Fertilizers and Chemical products. The company's product portfolio includes water soluble fertilizers, sulfur based products, seeds, soil conditioners, and micro nutrients. The company serves markets including Medical, Agriculture, Consumer Goods, Industrial Manufacturing and Construction. The company also provides services including national distribution, product selection, customized services, farmer training program, technical support and customer service.
Merck, started in 1668 and based in Darmstadt, Germany, is a supplier of solutions and services for research, development, and manufacture of pharmaceutical and biotechnological drug therapies. The company serves the life science industry and has a broad portfolio of 300,000 products, including biopharmaceutical manufacturing, industrial microbiology, reagent, life science research, and water purification products. It is available in 66 countries, brings together six brands, and has several ISO certifications, including ISO 13485, ISO 14001, ISO 13485, and ISO 50001.
Fibrant, established in 1952 and based in Urmond, The Netherlands, operates as both a manufacturer and supplier of chemical solutions. The company offers a product line that includes EcoLactam, an environmentally conscious Caprolactam used in sustainable nylon production, and Cyclohexanone, a vital component in Caprolactam manufacturing. It also specializes in Ammonium Sulfate technology, and collaborates with its business partners, across a significant portion of textile, automotive, food packaging, and agricultural chains.
Arihant Chemicals, founded in 2005 and located in Gujarat, India, is a manufacturer, distributor, and supplier of diverse chemical products. Its extensive product range encompasses various chemicals such as Ferrous Sulphate, Chloroform, Cyclohexanone, Methylene Chloride, and Borax Powder, among others. These chemicals serve multiple purposes, from water treatment to raw materials in industries like nylon production. The company maintains quality standards and holds ISO 9001:2008 certification, ensuring the consistency and effenciency of its products.
Hwatsi Chemical Private Limited, established in 2003 by Mr. Bharatkumar Sheth, based in Mumbai, India, is a supplier of solvent chemicals. The company manufactures various chemical products, including acetone, basic chrome sulfate, butyl glycol, butyl acrylate monomer, and isopropyl alcohol, among others. The company is ISO certified and rated by Crisil - high in finance. It was awarded the highest exports winner from the Government of India. The company has a global recognition in Turkey, Dubai, Nigeria, Australia and USA, among other countries.
Zhengzhou Meiya Chemical Products Co., LTD was founded in 2005 in Henan, China, and is headquartered in Zhengzhou, China. The company is a distributor and exporter of chemicals from China to Europe, Asia, and the Americas. The ISO 9001-certified company specializes in VOC-exempt solvents, paints and coatings, adhesives, PU, and resin for industries such as agriculture, pharmaceuticals, feed, water treatment, and oil field chemicals. The company’s product categories include plant extracts, cosmetics, PU, and resin.
Henan GP Chemicals Co., Ltd., established in 2014 with its head office in Zhengzhou and a secondary office in Henan, China, is a distributor of chemical products from China. The company offers over 1,000 products, including chlorinated paraffin, isobutyl isobutyrate, and trioctyl trimellitate. Henan GP Chemicals Co., Ltd.'s main products are used in solvents, plastics and rubber, adhesives, pharmaceuticals, and agriculture. The company also provides custom services that include business-to-business distribution solutions for industrial and specialty chemicals around the world.
Ranking as of November 2024
Derivation MethodRank | Company | Click Share |
---|---|---|
1 | SHANDONG SUNXI NEW MATERIAL CO.,LTD |
23.8%
|
2 | SANKYO CHEMICAL CO.,LTD. |
15.4%
|
3 | KANTO CHEMICAL CO.,INC. |
12.3%
|
4 | Zhengzhou Meiya Chemical Products Co.,Ltd. |
8.4%
|
5 | Gujarat State Fertilizers & Chemicals Limited |
8.4%
|
6 | Fibrant |
7.9%
|
7 | Henan GP Chemicals Co.,Ltd |
7.0%
|
8 | Merck |
7.0%
|
9 | Arihant Chemicals |
5.3%
|
10 | Hwatsi Chemical Private Limited |
4.4%
|
Derivation Method
The ranking is calculated based on the click share within the cyclohexanone page as of November 2024. Click share is defined as the total number of clicks for all companies during the period divided by the number of clicks for each company.Number of Employees
Newly Established Company
Company with a History
*Including some distributors, etc.
Country | Number of Companies | Share (%) |
---|---|---|
India | 3 | 42.9% |
Japan | 2 | 28.6% |
China | 2 | 28.6% |