This section provides an overview for phenolic resins as well as their applications and principles. Also, please take a look at the list of 13 phenolic resin manufacturers and their company rankings. Here are the top-ranked phenolic resin companies as of November, 2024: 1.Taiwan PU Corporation, 2.TRInternational, Inc., 3.SAE Manufacturing Specialties Corp.
Table of Contents
Graduated from Kyoto University, Faculty of Science, Graduate School of Science, Master (Chemistry). Joined a major general chemical manufacturer listed on the First section of the Tokyo Stock Exchange in April 2013. Engaged in analysis and scale-up of new functional polymers. Moved to another major manufacturer since May 2021. Specializes in analytical chemistry, physical chemistry, polymer chemistry, and polymer molding and processing.
https://www.linkedin.com/in/yuta-ishino-1bb143229/
Phenolic resins have excellent heat resistance, chemical resistance, and insulation properties and are used in a wide range of applications, such as automobiles, electronic components, and insulation materials. Phenolic resins are obtained through polymerization reactions using phenols and aldehydes as raw materials. Their physical properties can be changed by changing the chemical structures of the phenols and aldehydes used as raw materials and additives added to the resin and other factors.
Phenolic resins are classified into two types with different chemical structures: the novolac type obtained by acid catalyst reaction and the resol type obtained by base catalyst reaction. In the former, a curing reaction occurs when mixed with a curing agent such as epoxy resin and heated, while in the latter, a curing reaction occurs only by heating without a curing agent. Other differences include thermoplasticity in the novolac type and thermosetting in the resol type.
Phenolic resin is the world's first man-made plastic, invented by Bakelite in 1907. It has excellent heat resistance, chemical resistance, insulation, and mechanical strength and is still used in many industries. For example, phenolic resins are used in high-temperature process parts, such as resins for automobile brakes and the steel and glass industries. They are also used in insulation materials for housing and resins for photoresists.
Phenolic resins can change their physical properties by changing the chemical structure of the resins by changing the structure of phenols and aldehydes used as raw materials and by changing additives such as fillers. Therefore, selecting the optimal phenolic resin according to the required properties is necessary.
Phenolic resins obtained by reacting phenols with aldehydes include "novolac type" and "resol type". Novolac-type resins are obtained by reaction under an acid catalyst and are reusable thermoplastic resins. On the other hand, the result type is a non-reusable thermosetting resin obtained by using a base catalyst.
Novolac resins are cured by heating with a curing agent such as epoxy resin, resulting in a high molecular weight resin. On the other hand, in the case of the resol type, the curing reaction proceeds by heating or acid even in the absence of a curing agent. Therefore, resol resins may also change over time during storage, resulting in higher molecular weight.
Phenolic resins are obtained by the addition-condensation of phenols and aldehydes. The reaction of phenol and formaldehyde is introduced here as a typical example.
As mentioned above, the compounds obtained differ between acid and base catalysts. With an acid catalyst, an electrophilic substitution reaction occurs at the ortho or para position of the OH group of phenol, which reacts with formaldehyde. After the reaction, a condensation reaction occurs with another phenol to obtain a novolac resin.
On the other hand, when a base catalyst is used, multiple formaldehyde reacts with the benzene ring of phenol to produce an oily mixture called resol. When this is heated, the resolves react with each other to form a thermosetting resin called resin.
In this way, when acid and base catalysts are used, the bonding sites and amounts of phenols and aldehydes that react are different, and the structure and physical properties of the phenolic resin obtained are also different.
While phenolic resins have various advantages, they also have some disadvantages. For example, phenolic resins undergo hydrolysis when in contact with a strong base such as sodium hydroxide in the presence of water, resulting in the degradation of the resin.
In addition, the phenolic resin itself is colored yellow or reddish brown and turns black when oxidized, so there is a limit to the range of coloring possible. Phenolic resins are also hard but brittle.
*Including some distributors, etc.
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Capital Resin Corporation is a custom resins, coatings, and chemicals manufacturer established in 1976 and based in Columbus, Ohio. The company specializes in production operations for client companies in the agriculture, adhesives, personal care, and composites markets. The company’s product lineup includes phenolic and resorcinol resins, alkylated phenols, aromatic sulfonic acids, and polyurethanes used in industries like aerospace, defense, automotive, and electronics. As an ISO 9001 and SOCMA ChemStewards certified company, Capital Resin Corporation is equipped to provide technical integration services including research and development, as well as chemical storage, packaging, and transportation.
Based in Bayville, NY, SAE Manufacturing Specialties Corp. is an ISO-certified supplier and manufacturer of industrial equipment, chemicals, components, ordinance, electronics, and systems for industries ranging from aerospace to high tech to law enforcement. Examples of product offerings include raw materials, chemicals, and lubricants for industrial purposes to finished products such as security helmets for law enforcement, and military ordnances. SAE also provides research and development as well as technical support for other companies in similar industries.
TRInternational Inc., founded in 1994 and headquartered in Edmonds, Washington, is a supplier of ingredients, raw materials, and services in North America. Its diversified product portfolio includes chemicals, rubber, and paints used in industries like metalworking, water treatment, and industrial cleaning. It has over 20 stocking and import points across the United States and offers additional services like custom manufacturing, contract packaging, and proprietary formulation. The company is SBA, WOSB, and LGBTBE certified, and in 2018, it was ranked number 70 in the Top 100 Chemical Distributors in North America.
ASAHI YUKIZAI CORPORATION, formerly known as Asahi Organic Chemicals Industry, is a Japanese manufacturer headquartered in Taito-ku, Tokyo, and specializes in resins and plastic valves since its establishment in 1945. The company manufactures valve and piping systems, including manual & automatic valves, pipes, fittings, and mixers. It also offers various foundry materials such as resin and sand products for casting, along with functional resins which cater to housing, construction, and industrial applications. The company engages in the design and construction of water utility facilities & reuse of wastewater, industrial water & wastewater treatment, environmental pollution prevention & purification, and public sewage management.
Colibrys, a joint company established in 2001 and headquartered in Yverdon-les-Bains, Switzerland, is a manufacturer, designer, and supplier of micro-electro-mechanical system sensors and electronic machines. The company offers a wide range of products including mechanical power transmissions, power generation systems, and seismic sensors. These products are used in industries such as aerospace, defense, energy, and transportation. Their products are utilized for various applications including measuring acceleration, inclination, and seismic activity, enabling data collection for various critical applications. The company also offers services such as aerial refueling and air delivery systems.
Shri Shakti Enterprises is a manufacturer and supplier based in India, established in 2002, specializing in producing quality hydraulic and pneumatic equipment. Shri Shakti Enterprises offers a wide range of products, including hydraulic cylinders, power packs, pneumatic cylinders, and industrial valves. Their products cater to various industries such as construction, agriculture, and manufacturing. The company's aim is to provide solutions that enhance the efficiency and productivity of their clients' operations.
Taiwan PU Corporation, established in 1986 in Taichung, Taiwan, is a manufacturer and supplier of polyurethane products and equipment. The company's diverse product portfolio includes polyurethane sheets, rods, tubes, and custom-molded parts used in industries such as automotive, electronics, and construction. Taiwan PU's quality polyurethane materials provide great durability, insulation, and impact resistance, making them essential for various applications. The company also delivers tailor-made solutions that meet the specific needs of its clients, contributing to improved performance and reliability in its products and projects.
Polyols and Polymers is an Indian manufacturer and supplier of polyurethane systems, adhesives, and coatings such as including but not limited to aromatic and aliphatic polyisocyanates, polyether polyols, polyester polyols, MDI prepolymers. The company was established in 1991 and has since grown to become a global supplier of polyurethane systems, specialty chemicals, and adhesives. Their products are used in various industries, including automotive, construction, furniture, and insulation. The company's main products include polyurethane foams, coatings, adhesives, and elastomers. In 2019, the company was awarded the Frost & Sullivan Indian Polyurethane Systems Company of the Year Award.
Chiah Sin Industrial Co., Ltd. is a Taiwanese manufacturer and supplier of precision-machined plastic components such as gears, rollers, pulleys, and bearings used in various industries like automotive, electronics, and medical, including aerospace, automotive, and medical. Established in 1978, it expanded its operations to include a wide range of products for various industries. Their products are used in automotive, electronics, and construction. The company's main products include epoxy resins, polyurethane adhesives, and silicone sealants. In 2018, the company was awarded the Taiwan Excellence Award for its performance epoxy resin products.
Taiwan-based NANPAO Resins Chemical Group (NRCG) is a manufacturer and supplier of synthetic resins, speciality adhesives, liquid and powder coatings, and various construction materials including admixtures and grouts. The company was founded in 1963, when its dye and finishing factory was restructured to produce polyvinyl acetate adhesives. Companies in the footwear, automotive, furniture, construction, and technology industries are among the company's core clients. NRCG has factories in multiple countries including China, Vietnam, Indonesia, India, and the Philippines. These produce technologies used in medical and optical devices, as well as renewable energy sources.
Romit Resins Pvt. Ltd., established in the year 1980 in Pali, Maharastra, is a manufacturer and supplier of Phenol Formaldehyde Resins. The company's product portfolio includes Phenol Formaldehyde Resin and Furfuryl Alcohol. The Phenolic Resin offered by the company is used in tyre and belt manufecturing, cork industry, printing Inks, Metal Melting Crucibles and graphite moulding among others. Their product is also used in railway and Aircraft applications. It is an ISO 9001-2015 certified company headquartered in Navi Mumbai.
Qingdao Scienoc Chemical Co., Ltd., based in China, is a manufacturer of additives and specialty chemicals since 2002. The company's main products include sulfide compounds, polyimide monomers, photo acid generators, cationic photoinitiators, and electrochemical gas sensors. Its products find applications in various industries, including electronics, rosin, rubber, plastic, ink, coatings, adhesives, automobiles, electricity, pharmacy, lubricants, and gas detection. The company holds the ISO9001:2015 certification and its main markets include the USA, Asia, South America, and Africa.
SI Group, Inc. is a Texas manufacturer of chemical solutions originally established in 1906. The company specializes in process solutions, chemical intermediates, active pharmaceutical ingredients (APIs), and performance additives for clients in the oil and gas, plastics, pharmaceuticals, and tire industries. The company’s product lineup includes corrosion inhibitors for oilfield production and refining, chain extenders for plastics recycling, rubber modifiers for increasing the performance of industrial goods, and light stabilizers to reduce degradation from UV radiation. With office operations in three continents, SI Group runs facilities in nine countries and provides services to client companies around the world.
Ranking as of November 2024
Derivation MethodRank | Company | Click Share |
---|---|---|
1 | Taiwan PU Corporation |
11.9%
|
2 | TRInternational, Inc. |
10.0%
|
3 | SAE Manufacturing Specialties Corp |
9.1%
|
4 | Capital Resin Corporation |
8.2%
|
5 | CHIA HSIN RESINS CO., LTD. |
8.0%
|
6 | Shri Shakti Enterprises |
7.8%
|
7 | Qingdao Scienoc Chemical Co., Ltd |
7.4%
|
8 | SI Group, Inc. |
6.9%
|
9 | Asahi Organic Chemicals Industry |
6.9%
|
10 | Romit Resins Pvt. Ltd. |
6.6%
|
Derivation Method
The ranking is calculated based on the click share within the phenolic resin page as of November 2024. Click share is defined as the total number of clicks for all companies during the period divided by the number of clicks for each company.Number of Employees
Newly Established Company
Company with a History
*Including some distributors, etc.
*Including some distributors, etc.
Country | Number of Companies | Share (%) |
---|---|---|
United States of America | 3 | 25.0% |
India | 3 | 25.0% |
Taiwan | 3 | 25.0% |
Japan | 2 | 16.7% |
China | 1 | 8.3% |